Detrifluoroacetylation of 4,4,4-trifluoro-3,3-dihydroxy-2-(hydroxyimino)butan-1-ones as a convenient synthetic strategy for acyl cyanides / Bazhin Denis N.,Kudyakova Yulia S.,Nemytova Natalia A.,Burgart Yanina V.,Saloutin Victor I. // JOURNAL OF FLUORINE CHEMISTRY. - 2016. - V. 186, l. . - P. 28-32.

ISSN/EISSN:

0022-1139 / 1873-3328

Type:

Article

Abstract:

A reaction reinvestigation of fluorinated 1,3-dicarbonyl compounds with NaNO2 in acidic conditions revealed the formation of corresponding 1,1,1-trifluoro-3-hydroxyimino-butan-2,4-diones which predominantly isolated as hydrates. A novel synthesis of ethoxy-, alkyl-, (het)aryl substituted carbonylcyanides via acid-catalyzed detrifluoroacetylation of obtained 2-hydroxyimino derivatives of 1,3-dicarbonyl compounds was described. (C) 2016 Elsevier B.V. All rights reserved.

Author keywords:

Detrifluoroacetylation; 1,3-Dicarbonyl compounds; NaNO2; Carbonylcyanides ONE-POT SYNTHESIS; TUBERCULOSTATIC ACTIVITY; METHYL 3,3,3-TRIFLUOROPYRUVATE; ENANTIOSELECTIVE SYNTHESIS; ORGANIC-SYNTHESIS; PYRAZOLES; KETONES; TRIFLUOROMETHYL; ACID; HETEROCYCLES

DOI:

10.1016/j.jfluchem.2016.04.009

Web of Science ID:

ISI:000377321300005

Соавторы в МНС:

Другие поля

Поле	Значение
Month	JUN
Publisher	ELSEVIER SCIENCE SA
Address	PO BOX 564, 1001 LAUSANNE, SWITZERLAND
Language	English
EISSN	1873-3328
Keywords-Plus	ONE-POT SYNTHESIS; TUBERCULOSTATIC ACTIVITY; METHYL 3,3,3-TRIFLUOROPYRUVATE; ENANTIOSELECTIVE SYNTHESIS; ORGANIC-SYNTHESIS; PYRAZOLES; KETONES; TRIFLUOROMETHYL; ACID; HETEROCYCLES
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear; Chemistry, Organic
Author-Email	dnbazhin@gmail.com
ResearcherID-Numbers	Burgart, Yanina/T-8025-2017 Kudyakova, Yulia/J-7484-2016 Bazhin, Denis/P-4667-2014
ORCID-Numbers	Burgart, Yanina/0000-0001-6061-2410 Kudyakova, Yulia/0000-0003-0637-1606 Bazhin, Denis/0000-0003-3972-6995
Funding-Acknowledgement	Russian Foundation for Basic Research {[}16-33-60048 mol\_a\_dk]; President of the Russian Federation {[}1895.2016.4]
Funding-Text	Financial support from the Russian Foundation for Basic Research (grant no. 16-33-60048 mol\_a\_dk) is gratefully acknowledged. BDN is thankful for scholarship of President of the Russian Federation ( 1895.2016.4).
Number-of-Cited-References	52
Usage-Count-Last-180-days	3
Usage-Count-Since-2013	10
Journal-ISO	J. Fluor. Chem.
Doc-Delivery-Number	DN8IB