Determination of glycols in glycol-containing oligomers using gas-liquid reaction chromatography / Pervova M. G.,Plotnikova K. A.,Chizhov D. L.,Pestov A. V.,Saloutin V. I. // JOURNAL OF ANALYTICAL CHEMISTRY. - 2016. - V. 71, l. 6. - P. 630-636.

ISSN/EISSN:

1061-9348 / 1608-3199

Type:

Article

Abstract:

A method is proposed for the gas-chromatographic determination of glycols as bis(diethoxyphosphoryl) alkanes formed by the Atherton-Todd reaction with diethyl phosphite. Gas-chromatographic and mass-spectrometric characteristics of the derivatives obtained are studied. Conditions of the phosphorylation reaction are optimized. The method is applied to the determination of the residual amounts of glycols in oligomeric glycol-o-phthalates.

Author keywords:

gas chromatography; mass spectrometry; glycols; phosphorylation ETHYLENE-GLYCOL; MASS-SPECTROMETRY; DIETHYLENE GLYCOL; PROPYLENE-GLYCOL; TRACE AMOUNTS; DERIVATIZATION; URINE; WATER; PLASMA

DOI:

10.1134/S1061934816060137

Web of Science ID:

ISI:000377590500015

Соавторы в МНС:

Другие поля

Поле	Значение
Month	JUN
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
EISSN	1608-3199
Keywords-Plus	ETHYLENE-GLYCOL; MASS-SPECTROMETRY; DIETHYLENE GLYCOL; PROPYLENE-GLYCOL; TRACE AMOUNTS; DERIVATIZATION; URINE; WATER; PLASMA
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Analytical
Author-Email	pervova@ios.uran.ru
Funding-Acknowledgement	Russian Academy of Sciences, Ural Branch {[}NP-13-3-012-RTs]
Funding-Text	The work was supported by the Complex Research Program of the Russian Academy of Sciences, Ural Branch (project no. NP-13-3-012-RTs).
Number-of-Cited-References	21
Usage-Count-Last-180-days	3
Usage-Count-Since-2013	5
Journal-ISO	J. Anal. Chem.
Doc-Delivery-Number	DO2DS