Single particle structure characterization of solid-state synthesized Li4Ti5O12 / Pelegov D.V., Slautin B.N., Zelenovskiy P.S., Kuznetsov D.K., Kiselev E.A., Alikin D.O., Kholkin A.L., Shur V.Y. // Journal of Raman Spectroscopy. - 2017. - V. 48, l. 2. - P. 278-283.

ISSN:
03770486
Type:
Article
Abstract:
Synthesis of any material results not only in the fabrication of the desired composition, but also some amount of undesired second phases. Here we demonstrate that structural heterogeneity in a negative electrode material Li4Ti5O12 with sub-micron grain size synthesized using standard solid-state method can be described locally via structural characterization of single particles using a combination of standard micro-Raman spectroscopy together with scanning electron microscopy. Proposed approach can be used as a kind of low-cost alternative to high-resolution transmission electron microscopy for local structural characterization and a supplement to integral X-ray diffraction techniques not only for Li4Ti5O12, but also for a wide range of commercial products. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd.
Author keywords:
Li2TiO3; lithium titanate; local heterogeneity; single particle characterization; TiO2
Index keywords:
нет данных
DOI:
10.1002/jrs.4999
Смотреть в Scopus:
https://www.scopus.com/inward/record.uri?eid=2-s2.0-84979788603&doi=10.1002%2fjrs.4999&partnerID=40&md5=64f4b2158b38d940a1c85bdf6887ae8f
Соавторы в МНС:
Другие поля
Поле Значение
Link https://www.scopus.com/inward/record.uri?eid=2-s2.0-84979788603&doi=10.1002%2fjrs.4999&partnerID=40&md5=64f4b2158b38d940a1c85bdf6887ae8f
Affiliations Institute of Natural Sciences, Ural Federal University, Ekaterinburg, Russian Federation; Department of Physics and CICECO – Materials Institute of Aveiro, University of Aveiro, Aveiro, Portugal
Author Keywords Li2TiO3; lithium titanate; local heterogeneity; single particle characterization; TiO2
Funding Details FEDER, Federación Española de Enfermedades Raras; 1366.2014/236, Minobrnauka, Ministry of Education and Science of the Russian Federation
Funding Text The authors thank V. S. Gorshkov, JSC Eliont, for his invaluable help in sample synthesis and discussions. The equipment of the Ural Center for Shared Use ‘Modern nanotechnology’ UrFU was used. The work was supported by Government of the Russian Federation (Act 211, Agreement 02.A03.21.0006). Vladimir Shur acknowledges financial support within the State Task from the Ministry of Education and Science of Russian Federation (Project No. 1366.2014/236). Part of this work was developed in the scope of the project CICECO-Aveiro Institute of Materials (Ref. FCT UID/CTM/50011/2013), financed by national funds through the FCT/MEC and when applicable co-financed by FEDER under the PT2020 Partnership Agreement.
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Correspondence Address Pelegov, D.V.; Institute of Natural Sciences, Ural Federal UniversityRussian Federation; email: dmitry.pelegov@urfu.ru
Publisher John Wiley and Sons Ltd
CODEN JRSPA
Language of Original Document English
Abbreviated Source Title J. Raman Spectrosc.
Source Scopus